CHEMISTRY FORM THREE-TOPIC 4: THE MOLE CONCEPT AND RELATED CALCULATIONS.

TOPIC 4: THE MOLE CONCEPT AND RELATED CALCULATIONS.

The Mole as a Unit of Measurement

When carrying out an experiment, a chemist cannot weigh out a single atom, ion, electron, proton or molecule of a substance. These particles are simply very small. A counting unit that is useful in practical chemistry must be used.The standard unit is called one mole of the substance. One mole of each of these different substances contains the same number of the particles (atoms, molecules, ions, electrons, protons, neutrons, etc). That number per mole has been worked by several different experimental methods and is found to be 6.0 × 1023.

The value 6.0 × 1023 is called Avogadro’s constant or Avogadro’s number and is abbreviated as L. It is named after the nineteenth-century Italian chemist, Amedeo Avogadro.The value 6.0 × 1023 is obtained through the following relationship.The mass of one atom of carbon-12 is 1.993 × 10-23g. Then, the number of atoms present in 12g of carbon-12 is derived as follows:1 atom = 1.993 × 10-23gX atoms = 12g

X = 6.0 × 1023 atoms.Therefore, the number of atoms in 12g of carbon-12 and hence the number of particles in a mole are 6.02 × 1023 atoms.

Hence, Avogadro’s number is the number of atoms in exactly 12g of carbon-12 isotope.One mole of any substance contains as many as many elementary particles as the Avogadro’s number (constant).So, from the above explanation, the mole can be defined as the amount of a substance that contains as many elementary particles as the number of atoms present in 12g of carbon-12 isotope.

The other substances, which also exist as molecules, include ozone molecule (gas), O3; phosphorus molecule (solid), P4; sulphur molecule, S8, etc.

In real life, when dealing with large numbers of small objects, it is usual to count them in groups. The objects are grouped and counted in unit amounts. For example, we buy a carton of soap, a gallon of
kerosene, a crate of soda, a dozen of pencils, a ream of papers, etc.

Some units of measurement

Molar Quantities of Different Substances

The mass of one mole of any substance (its molecular mass) is the atomic mass or molecular mass expressed in grams (or kilograms). For convenience, chemists prefer to express mass in grams, although the SI unit of mass is the kilogram. This is because the amount of substances which chemists usually work with in science laboratories, is quite small and if their masses are expressed in kilograms, the numbers used would be extremely small.You can calculate the molar mass (M) of any substance by summing up the relative atomic weights of its constituents atoms. For example, ethanol, C2H5OH, contains two carbon atoms, six hydrogen atoms and one oxygen atom. So, the molar mass of ethanol can be calculated thus: Molar mass of C2H5OH = (2 × 12) + (6×1) + 16 = 46g.In a similar way, molar masses of other compounds can be calculated. For example, the molar mass of sodium chloride, NaCl, is calculated by adding together the relative atomic masses of the constituents elements (Na = 23 and Cl = 35.5) = 23 + 35 = 58.5g (g mol-1).It is important to note that relative atomic mass or relative molecular mass has no unit while molar masses are always expressed in grams or kilograms.The molar massof a compound is the same as the relative molecular mass and the molar massof anelement is the same as the relative atomic mass (Ar) of that element. The only difference lies in the units.Example 1

• M(CO2) = 44g (or g mol-1) = molar mass of carbon dioxide
• Mr(CO2) = 44 = relative molecular mass of carbon dioxide
• M(Fe) = 56g (or g mol-1) molar mass of iron
• Mr(Fe) = 56 = Relative atomic mass of iron

Similarly, the molar masses of each of the following substances can be calculated using values for the relative atomic masses of the elements.

Molar masses of different substances

Application of the Mole Concept

Known Masses of Elements, Molecules or Ions to Moles Convert known masses of elements, molecules or ions to moles

In experimental work, chemists work with varying masses. They cannot always use one mole of a substance. The equation that links the mass of a substance to the number of moles present is:

Example 2Convert 49g of sulphuric acid, H2SO4, into moles.Given:Mass = 49g; molar mass = 98gFormula:

Solution: 49g of H2SO4= 49/98= 0.5 mol. Known Volumes of Gases at S.T.P to Moles Convert known volumes of gases at S.T.P to moles

The volume occupied by one mole of a gas at standard condition of temperature and pressure has been scientifically determined, and it is found to be 22.4 dm3. This volume is called the molar volume of a gas. The molar volume of a gas, therefore, has the value of 22.4 dm3 at s.t.p. Remember that 1 dm3 (1 litre) = 1000 cm3. One important thing about this value is that it applies to all gases. Therefore, at s.t.p. 32g of oxygen (O2) or 17g of ammonia (NH3) or 44g of carbon dioxide (CO2) or 40g of argon (Ar) will occupy a volume of 22.4 dm3.
This makes it easy to convert the volume of any gas at s.t.p. into moles, or moles into volume. However, it is important to note that as the conditions of temperature and pressure change the molar volume will also change.The number of moles of a given sample of gas is obtained by dividing the volume of the gas by molar volume (22.4 dm3).

For example, 4.4d m3 of carbon dioxide gas at s.t.p. = 4.4/22.4= 0.196 mol.Similarly, 2.24 dm3 of neon gas at s.t.p. = 2.24/22.4= 0.1 mol.If the volume of the gas is given in cm3, then it should be divided by the molar volume of a gas expressed in cm3. For example, 560 cm3 of nitrogen gas = 560cm3/22400cm3 mol= 0.025 mol.Alternatively, the volume may, first, be converted to dm3 and then divides by the molar volume, expressed in dm3, that is, 0.46dm3/22.4dm3 = 0.25molMasses of Solids or Volumes of Known Gases to Actual Number of PartiesChange masses of solids or volumes of known gases to actual number of partiesThe number of particles in one mole of any substance is 6.02 × 1023. To find the number of particles in a substance, we use the expression:

• N = n.L, where
• N = the number of particles in that substance;
• n = the amount of substance (moles); and
• L = the Avogadro’s constant (6.02 × 1023).

This conversion requires two steps: first convert the mass of solid or volume of gas to moles, and then multiply the number of moles by the
Avogadro’s constant. For example, to convert 5.6 dm3 of ammonia gas to the actual number of ammonia (NH3) molecules, change 5.6 dm3 of ammonia to moles =0.46dm3/22.4dm3=0.25 mol. Then multiply by the Avogadro’s constant to get the total number of molecules0.25 × 6.02 × 1023 = 1.5 × 1023 molecules

Similarly, 1.12 dm3 of hydrogen gas = 1.12/22.4= 0.05 mol. This is equal to 0.05 × 6.02 × 1023 = 3.0 ×1022 molecules

Alternatively, we may find out the number of particles by converting the given volume to the number of molecules straight forward without passing through the number of moles first. We know that one mole (22.4 dm3) of a gas at s.t.p. = 6.02 × 1023 molecules. So, 5.6 dm3 = 5.6×6.02 × 1023/22.4= 1.5 × 1023 molecules

Molar Solutions of Various Soluble Substances

A molar solution is a solution which contains one of the compound in one litre (1 dm3 or 1000 cm3) of the solution.Let us consider the case of sodium hydroxide, NaOH. The molecular weight of this compound is 40g. Therefore, a molar solution
of sodium hydroxide will contain 40g in 1000 cm3(1 dm3) of the solution.Also, consider anhydrous sodium carbonate, Na2CO3. 1 mole of this carbonate weights 106g. Hence, its molar solution will contain 106g of the anhydrous salt in 1000 cm3 of solution.If, however, 0.1 moles (10.6g) of the solute is dissolved in 1.0 dm3, the solution is 0.1 molar. But if 0.1 moles is dissolved in 0.1 dm3 of the solution, the solution is still 1.0 molar (since 1 dm3 of solution would contain 1.0 mole of the solute).The molecular weights of some common substances are shown below:

The molar solution of each of these substances can be prepared by dissolving one mole of each substance in 1000 cm3 (1 dm3) of distilled water. We see, therefore, that 40g of sodium hydroxide in 1000 cm3 of solution will give a 1.0M solution. Hence, 20g of the hydroxide should give a 0.5M solution. In a similar way, we can make derivative solution concentrations ranging as follows: 0.1M, 0.2M, 0.3M, 0.4M….1M, 2M, etc.However, in each case the amount of solution should always be 1000 cm3. The concentration ranges like these are known as molarities of solutions. Hence, 0.5M sodium carbonate can also be read as “a sodium carbonate solution with a molarity of 0.5M.”

The Concentration of Solutions

When a chemical substance (the solute) is dissolved in a given volume of solvent, we can measure the “quantity” of solute in two ways; we can measure either its mass (in grams) or its amount (in moles). The final volume of the solution is usually measured in dm3.When we measure the mass of the solute in grams, we obtainthe mass concentration in g/dm3

Example 3. Calculate the concentration (g/dm3) of sodium chloride solution (NaCl) that contains 20g of sodium chloride in a final solution of 100 cm3

Solution. First, convert the given volume to dm3Volume (dm3) = 100/1000= 0.1 dm3Then, work out the concentration of the solution by dividing the mass (weight) of solute (g) by the volume (dm3).

=20g/0.1dm3= 200g/dm3Alternatively, we could calculate the concentration straightforward without having to convert the given volume into dm3, e.g.:If 20g of the solution are contained in 100 cm3 of the solution, then the amount of solute in 1000 cm3 (1 dm3) of the solution would be1000×20/100 = 200g/dm3

Calculations Based on the Mole Concept

A chemist always wants to know how much of one substance would react with a given amount of another substance. This is achieved by use of balanced chemical equations. Such equations are called stoichiometric equations. A stoichiometric equation is the one in which the reactants and the products are correctly balanced; all the atoms, ions and electrons are conserved. Such an equation gives correct mole ratios of reactants and products in chemical reactions. This quantitative relationship is called
stoichiometry.Consider an equation for the reaction between hydrogen and nitrogen to produce ammonia:3H2(g) + N2(g)→ 2NH3This can be read as follows:three moles of hydrogen reacts with one mole of nitrogen to yield two moles of ammonia.The
numbers 3, 1 and 2 are called stoichiometric coefficients. They tell us the proportions in which the substances react and in which the products are formed.Example 4What volume of carbon dioxide (CO2) measured at s.t.p. will be produced when 21.0g of sodium hydrogencarbonate (NaHCO3) is completely decomposed according to the equation. 2NaHCO3(s)→ Na2CO3(s) + CO2(g) + H2O(l)

Solution. First, find the weight of carbon dioxide that will be produced by the hydrogencarbonate.

• Mass of 2NaHCO3 = 2 × 84 = 168g
• Mass of CO2 = 44g

The weight of carbon dioxide produced can be obtained from the following relation:168g ≡ 44g21g ≡ XX = 21×44/168 = 5.5gThe weight of carbon dioxide produced = 5.5gThen, convert this weight of CO2 to volume at s.t.p.We know that one mole (44g) of carbon dioxide at s.t.p. occupies 22.4 dm3That is, 44g ≡ 22.4dm35.5g ≡ X dm3X = 5.5×22.4/44 = 2.8dm3